MIT Open Access Articles

The MIT Open Access Articles collection consists of scholarly articles written by MIT-affiliated authors that are made available through DSpace@MIT under the MIT Faculty Open Access Policy, or under related publisher agreements. Articles in this collection generally reflect changes made during peer-review.

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  • Room‐Temperature Copper‐Catalyzed Etherification of Aryl Bromides 

    Strauss, Michael J; Greaves, Megan E; Kim, Seoung‐Tae; Teijaro, Christiana N; Schmidt, Michael A; e.a. (Wiley, 2024-02-15)
    We disclose the development of a Cu-catalyzed C−O coupling method utilizing a new N1,N2-diarylbenzene-1,2-diamine ligand, L8. Under optimized reaction conditions, structurally diverse aryl and heteroaryl bromides underwent ...

  • CuH-Catalyzed Regio- and Enantioselective Formal Hydroformylation of Vinyl Arenes 

    Garhwal, Subhash; Dong, Yuyang; Mai, Binh Khanh; Liu, Peng; Buchwald, Stephen L (American Chemical Society, 2024-05-09)
    A highly enantioselective formal hydroformylation of vinyl arenes enabled by copper hydride (CuH) catalysis is reported. Key to the success of the method was the use of the mild Lewis acid zinc triflate to promote the ...

  • Cu-Catalyzed Amination of Base-Sensitive Aryl Bromides and the Chemoselective N- and O-Arylation of Amino Alcohols 

    Strauss, Michael J; Liu, Kaylee X; Greaves, Megan E; Dahl, Jakob C; Kim, Seoung-Tae; e.a. (American Chemical Society, 2024-06-26)
    We report a general and functional-group-tolerant method for the Cu-catalyzed amination of base-sensitive aryl bromides including substrates possessing acidic functional groups and small five-membered heteroarenes. The ...

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