Construction of prototype system for directional solvent extraction desalination

Abstract

Directional solvent extraction has been demonstrated as a low temperature, membrane free desalination process. This method dissolves the water into an inexpensive, benign directional solvent, rejects the contaminants, then recovers pure water, and re-uses the solvent. In order to bring this technology closer to real world application, a continuous process prototype for a directional solvent extraction system was developed and tested. Octanoic acid was used as the solvent of choice, and a system capable of producing up to 7 gallons per day of fresh water was constructed. The system was tested to effectively desalinate the feed water, and the total system power was less than 7 kW. The system was constructed and first tested to run fresh water and solvent through it. Fresh water was dissolved in and separated, as expected, from the solvent at a rate of about 2 gpd. Saline water containing 3.5% sodium chloride was then used as feedwater and the desalinated water was recovered at a rate of about 1 gpd with an average salinity of 0.175%. Effective continuous operation of the directional solvent extraction prototype was demonstrated. Certain design improvements to increase efficiency, optimize component sizes, and decrease energy consumption are suggested. The demonstrated system has a wide range of applications, including production of fresh water from the sea, as well as, treatment of produced and flowback water from shale gas and oil extraction.